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Than the TePP and you will pentaphenylpyrrole (PPP), one another TPM and TPM-Cl displayed prolonged emission wavelengths. Because of the similar chemical compounds formations, this is not plausible to attribute the important Stokes shift so you can differences in the energy pit between your lowest singlet delighted state (S1) and you may crushed state (S0). I for this reason suggest that the new reddish emission represents a low triplet delighted state (T1), which is lower than S1. dos, where the contours are the same on the constant-county emission spectra, discussing the new long life functions away from each other TPM and TPM-Cl. The fresh lifetimes of your own TPM and you can TPM-Cl crystalline powders is 20.1 and you may 8.9 μs, respectively (Fig. S3 and you may Dining table S1).
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Chongqing Wulong Karst Area, Wulong Karst Landscaping
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